Electrochemical Nature of Corrosion

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Last updated on May 26, 2026 12:53 pm

Learn about forms of corrosion and how to derive the Nernst equation while studying the construction of Pourbaix diagrams and the mixed potential theory.

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This free online course on the electrochemistry of corrosion teaches you about the processes that can cause corrosion, as well as the impact of different forms of corrosion and how to derive the important Nernst equation. You will learn about the steps for constructing a Pourbaix diagram and be able to explain the relevance of the mixed potential theory.

What You Will Learn In This Free Course

  • Explain how each form of corrosion a…
  • Outline the different aspects of the…
  • Discuss the relationship between fre…
  • Explain how the spontaneity of corro…
  • Explain how each form of corrosion affects the surrounding areas
  • Outline the different aspects of the thermodynamics of corrosion
  • Discuss the relationship between free energy and the equilibrium constant
  • Explain how the spontaneity of corrosion occurs in any situation
  • Discuss the relevance of the Pourbaix diagram
  • Outline the steps for constructing the Pourbaix diagram for a Ni-H2O system
  • Outline the step by step process to deriving the Nernst equation for any particular system
  • Discuss the concept of kinetics or the rate of corrosion
  • Explain the relevance of the exchange current density in corrosion
  • Outline how the Butler-Volmer equation is used to derive the Nernst equation
  • Identify the role played by the mixed potential theory in determining the corrosion rate
  • Corrosion and its Forms

    In this module, you will be introduced to the concept of corrosion, as well as the various processes that can cause corrosion. You will also be introduced to the different types of corrosion which are uniform, galvanic, crevice, and pitting corrosion, as well as the impact of each type of corrosion.

    Thermodynamics of Corrosion

    In this module, you will be introduced to the different forms of corrosion, as well as the electrochemical nature of corrosion and its thermodynamics. You will also be introduced to the thermodynamics aspects of corrosion, the concept of free energy change, as well as the process of entropy change.

    Nernst Equation in Standard Reduction Potential

    In this module, you will be introduced to the relationship between free energy and the equilibrium constant, as well as how the Nernst equation can be derived for a reaction. You will also be introduced to the standard reduction potential series for pure metals, as well as the reduction potentials in acidic and neutral solutions.

    Corrosion Process and Pourbaix Diagram

    In this module, you will be introduced to the various limitations of standard reduction potential series of pure metals, as well as the concept of concentration cell formation. You will also be introduced to the galvanic series, some examples of concentration cells, as well as the spontaneity of the corrosion process and Pourbaix diagrams.

    Diploma in Electrochemistry of Corrosion – First Assessment

    You need to score 80% or more to pass.; Module

    Construction of Pourbaix Diagrams

    In this module, you will be introduced to the construction of the Pourbaix diagram for a Ni-H2O system, as well as happens when the pH concentration of the H+ ion increases. You will also be introduced to the positions where the acidic reactions and basic reactions will happen, as well as the schematic phase diagram for aluminium.

    Corrosion Rate Measurements

    In this module, you will be introduced to the steps used in the estimation of corrosion rate, as well as kinetics or rate of corrosion and the rate of dissolution of metal. You will also be introduced to the steps for calculating the corrosion rate in the form of mass loss per area per unit time.

    Equations for Measuring Corrosion Rate

    In this module, you will be introduced to the concept of the electrode double layer, as well as the different types of polarization and the correlation between current density and overvoltage. You will also be introduced to the derivation of the Butler-Volmer equation, as well as how the Tafel equation is derived.

    Introduction to Mixed Potential Theory

    In this module, you will be introduced to the concepts of activation polarization and concentration polarization, as well as total polarization. You will also be introduced to the derivation of the mixed potential theory, as well as some case studies that highlight the mixed potential theory and the events of corrosion.

    Diploma in Electrochemistry of Corrosion – Second Assessment

    You need to score 80% or more to pass.; Module

    Course assessment

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      Electrochemical Nature of Corrosion
      Electrochemical Nature of Corrosion
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